Fire Safety – Remove TB117

A California furniture flammability standard called Technical Bulletin 117 (TB117) has led to the use of toxic or untested flame retardant chemicals at high levels in furniture and baby product foam1,2 across the USA and Canada since 1975.

The major flame retardant chemicals used in foam to meet TB117 are associated with adverse health effects

  • PentaBDE has been linked to decreased fertility3, hormone disruption4, lowered IQ5,6 and hyperactivity7 in humans. In animal studies, this chemical causes reproductive, thyroid, hormonal, developmental and neurological disorders8. It is one of 21 chemicals globally banned by the Stockholm Convention on Persistent Organic Pollutants, signed by 177 countries

  • Chlorinated Tris or TDCPP was voluntarily removed from children’s sleepwear in the 1970s because it changed DNA9.  It was listed as a carcinogen under California’s Proposition 65 in 201110.

  • Firemaster 550 contains four flame retardant ingredients which are known to be toxic or lack adequate toxicity information11–13.  A pilot study links low level exposures to obesity and anxiety in animals14.

  • Halogen-free replacements for banned flame retardants are also not proven safe. Some halogen-free alternatives show neurotoxicity and ecotoxicity while others have little information available15.

Flame retardants move from products into the environment and into people, pets and wildlife

  • Because of TB117, most U.S. furniture and baby products contain flame retardants in the foam and pounds of these chemicals can be found in homes and offices. They continuously migrate out of products into dust16 (Figure 1)17 and are ingested by humans18 and pets19,20.

  • Californians have among the highest levels of pentaBDE measured in the world in their household dust and bodies21 (Figure 1).

  • Retardant chemicals cross the placenta and babies are born with the chemicals in their bodies22. Babies and toddlers are further exposed from their mother’s milk and household dust, which they ingest at higher levels due to their hand-to-mouth behavior. Consequently, young children have three times the levels of retardant chemicals in their bodies compared to their mothers23.

  • The average lifetime of upholstered furniture is 30 years and lower income households have older furniture containing pentaBDE. Thus those with lower income, and especially children, have increasingly high levels of this toxic retardant chemical in their bodies compared to those in higher income households24.

  • Flame retardant chemicals are found in air, wastewater from homes, and landfill leachates25–27. The chemicals contaminate soil, rivers, the ocean, fish, marine mammals and the food supply28. “Fireproof killer whales” and other marine mammals along the California coast contain the highest reported levels in the world of pentaBDE in their body fluids29.

Flame retardants as used to meet TB117 do not provide a fire safety benefit

  • TB117 requires the foam inside furniture to withstand a 12-second exposure to a small open flame. However in a real-life fire, fabric ignites first, exposing the interior foam to a much larger flame30. When this happens, flame retardants in foam do not prevent ignition of the foam or reduce the severity of the fire31–33.

  • When foam containing flame retardants burns, it can give off higher levels of carbon monoxide, soot, and smoke compared to untreated foam (Figure 2)34. The majority of residential fire deaths result from inhalation of toxic gases, soot and smoke35.

  • When pentaBDE, Firemaster 550 and other related retardant chemicals burn, they produce high levels of dioxins and furans, compounds that are known to cause cancer. Firefighters have elevated rates of cancers that are associated with exposure to dioxins/ furans36.

  • Upholstered furniture fires started by smoking materials, the leading cause of furniture fire deaths, have fallen sharply since 1980. No change was seen for upholstered furniture fire deaths started by small open flames (candles, lighters, matches), the type of fires that should have been addressed by TB117 (Figure 3)37.

  • Since 2007, there have been four bills introduced to change TB117 through the California legislature. The flame retardant industry spent a documented 23.2 million dollars on lobbying to defeat these bills38.

  • Since most furniture fires are caused by cigarettes and begin in fabric, the California Bureau of Electronic and Appliance Repair, Home Furnishing and Thermal Insulation proposed to change the current TB117 open-flame test to a smolder standard for fabric (TB 117-2013). This would improve fire safety without the need for toxic retardant chemicals.  The CPSC published a similar draft standard in 2008 and predicted:

    • The vast majority (85%) of upholstered furniture currently on the market would already be in compliance because existing cover fabrics meet the proposed requirements without added chemicals.

    • The remaining upholstered furniture would likely be redesigned with the use of
      smolder proof fabrics, batting (10%) or barriers (5%).

GLOSSARY:

Flame retardant (FR)

A chemical added to a material (e.g., foam or plastic) to change its flammability properties and reduce its ability to ignite and/or burn. Flame retardant chemicals are usually used to meet the requirements of a mandated flammability test (e.g., must withstand a 12 second exposure to a small open flame to meet the California furniture flammability standard TB117).

Halogenated FRs

Chemicals used for flame retardant purposes containing halogen atoms (typically either bromine or chlorine) substituting for hydrogen in an organic molecule.

Brominated FRs; FR chemicals involving partial or full substitution of hydrogen by bromine in an organic molecule.

Chlorinated FRs: FR chemicals involving partial or full substitution of hydrogen by chlorine in an organic molecule.

Polybrominated diphenyl ethers (PBDEs)

Structurally similar to the carcinogenic compounds dioxins and furans, PBDEs are compounds with one to ten bromine atoms arranged around two benzene rings joined by an oxygen atom.

Three commercial mixtures (i.e., pentaBDE, octaBDE, and decaBDE, named after the average number of bromine atoms attached were among the most commonly used FR:

PentaBDE: contains PBDE molecules with four, five, and six bromine atoms per molecule; was used primarily in furniture foam, carpet padding, and vehicles in North America. It has been linked to decreased fertility, hormone disruption, lowered IQ and hyperactivity

OctaBDE: contains PBDE molecules with six to ten bromine atoms; used primarily in manufactured plastic products – in particular acrylonitrile-butadiene-styrene (ABS) polymers in computer casings and monitors.

DecaBDE: composed mostly of BDE-209 with ten bromine atoms; used primarily in hard plastic, fabric back-coating, and electronics.

When burned, PBDEs can produce highly toxic brominated dioxin and furan compounds. Due to their toxicity and persistence, pentaBDE and octaBDE are no longer manufactured in the U.S. or the European Union (EU). DecaBDE will be voluntarily phased out in the U.S. by 2013. PentaBDE and octaBDE commercial mixtures are also among a short list of chemicals targeted globally to be eliminated from production and use by the Stockholm Convention on Persistent Organic Pollutants.

Halogenated organophosphate FRs

A number of halogenated organophosphate flame retardants, often referred to simply as Tris, have been used in a wide range of consumer products. Below are the most popular ones, their uses, and what is known about their health effects.

TDBPP (or TDBP), Brominated Tris, tris(2,3-dibromopropyl)phosphate. TDBPP was removed from children’s sleepwear in the 1970s due to its mutagenicity and likely carcinogenicity. It is listed as a carcinogen under California’s Proposition 65.

TDCPP (or TDCP), Chlorinated Tris, tris(1,3-dichloro-2-propyl)phosphate: Commonly used in furniture, carpet, and transportation foams as well as in baby products. TDCPP was voluntarily removed from children’s sleepwear in the 1970s. It is listed as a carcinogen under California’s Proposition 65; according to conclusions form a 2008 EU risk assessment it meets the criteria for persistence.

TCEP, tris(2-chloroethyl)phosphate: Has been used in rigid foam, but its use has declined significantly since being listed as a carcinogen in the European Union and under California’s Proposition 65. In 2011, it was also banned from use in children’s products in New York.

TCPP, tris(1-chloro-2-propyl)phosphate: Used in blown-in insulation and in foam. It has unknown health effects.

Dioxins and furans

Very toxic compounds produced inadvertently, such as through incomplete combustion of wood, fossil fuels and other organic chemicals. When halogens are present (e.g., chlorinated or brominated FRs), highly toxic and persistent compounds can be produced, such as polychlorinated dibenzo-p-dioxins and polybrominated dibenzo-p-dioxins.

ADDITIONAL RESOURCES:

Playing with Fire (Chicago Tribune special on flame retardants)  http://media.apps.chicagotribune.com/flames/index.html
Are You Safe on that Sofa? (The New York Times Op-Ed)
http://www.nytimes.com/2012/05/20/opinion/sunday/kristof-are-you-safe-on-that-sofa.html?_r=2&ref=opinion
Chemical Burns (The New York Times Op-Ed)  http://www.nytimes.com/2006/11/19/opinion/19blum.html

San Antonio Statement on Brominated and Chlorinated Flame Retardants signed by 220 scientists
Published in Environmental Health Perspectives http://ehp03.niehs.nih.gov/article/info:doi/10.1289/ehp.1003089
Identification of Flame Retardants in Polyurethane Foam Collected from Baby Products
Published in Environmental Science & Technology  http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3113369/?tool=pubmed

TEDx video presentation: 15 minute overview of the flame retardant problem http://www.youtube.com/watch?v=6IDlb4N-_u4
CITRIS Seminar: 45 minute presentation on risks and benefits associated with flame retardants
http://www.youtube.com/watch?v=A5njba_nhgc

REFERENCES

1. Stapleton HM, Klosterhaus S, Keller A, Ferguson PL, Van Bergen S, Cooper E, et al. Identification of flame retardants in polyurethane foam collected from baby products. Environmental science & technology. 2011 Jun 15;45(12):5323–31.

2. Stapleton HM, Sharma S, Getzinger G, Ferguson PL, Gabriel M, Webster TF, et al. Novel and High Volume Use Flame Retardants in US Couches Reflective of the 2005 PentaBDE Phase Out. Environmental science & technology. American Chemical Society; 2012 Nov 28;

3. Meeker JD, Johnson PI, Camann D, Hauser R. Polybrominated diphenyl ether (PBDE) concentrations in house dust are related to hormone levels in men. The Science of the total environment. 2009 May 1;407(10):3425–9.

4. Chevrier J, Harley KG, Bradman A, Gharbi M, Sjödin A, Eskenazi B. Polybrominated diphenyl ether (PBDE) flame retardants and thyroid hormone during pregnancy. Environmental health perspectives. 2010 Oct;118(10):1444–9.

5. Herbstman JB, Sjödin A, Kurzon M, Lederman SA, Jones RS, Rauh V, et al. Prenatal exposure to PBDEs and neurodevelopment. Environmental health perspectives. 2010 May;118(5):712–9.

6. Eskenazi B, Chevrier J, Rauch SA, Kogut K, Harley KG, Johnson C, et al. In Utero and Childhood Polybrominated Diphenyl Ether (PBDE) Exposures and Neurodevelopment in the CHAMACOS Study. Environmental health perspectives. 2012;(November).

7. Roze E, Meijer L, Bakker A, Van Braeckel KNJA, Sauer PJJ, Bos AF. Prenatal exposure to organohalogens, including brominated flame retardants, influences motor, cognitive, and behavioral performance at school age. Environmental health perspectives. 2009 Dec;117(12):1953–8.

8. Shaw SD, Blum A, Weber R, Kannan K, Rich D, Lucas D, et al. Halogenated flame retardants: do the fire safety benefits justify the risks? Reviews on environmental health. 2010;25(4):261–305.

9. Gold MD, Blum A, Ames BN. Another flame retardant, tris-(1,3-dichloro-2-propyl)-phosphate, and its expected metabolites are mutagens. Science (New York, N.Y.). 1978 May 19;200(4343):785–7.

10. OEHHA. OEHHA Proposition 65 tris(1,3-dichloro-2-propyl) phosphate (TDCPP) [Internet]. Office of Environmental Health Hazard Assessment. 2011 [cited 2012 Jul 20]. Available from: http://oehha.ca.gov/prop65/prop65_list/102811list.html

11. Bearr JS, Stapleton HM, Mitchelmore CL. Accumulation and DNA damage in fathead minnows (Pimephales promelas) exposed to 2 brominated flame-retardant mixtures, Firemaster 550 and Firemaster BZ-54. Environmental toxicology and chemistry / SETAC. 2010 Mar;29(3):722–9.

12. Chemtura. Material Safety Data Sheet #694. 2006. p. Product: Durad 150.

13. US EPA. Furniture flame retardancy partnership: environmental profiles of chemical flame-retardant alternatives for low-density polyurethane foam. U.S. Environmental Protection Agency; 2005. p. 4.2–4.5.

14. Patisaul HB, Roberts SC, Mabrey N, McCaffrey KA, Gear RB, Braun J, et al. Accumulation and Endocrine Disrupting Effects of the Flame Retardant Mixture Firemaster(®) 550 in Rats: An Exploratory Assessment. Journal of biochemical and molecular toxicology. 2012 Nov 8;

15. Waaijers SL, Kong D, Hendriks HS, De Wit CA, Cousins IT, Westerink RHS, et al. Persistence, Bioaccumulation, and Toxicity of Halogen-Free Flame Retardants. Whitacre DM, editor. Reviews of Environmental Contamination and Toxicology.  Springer New York; 2013;222:1–71.

16. Jones-Otazo HA, Clarke JP, Diamond ML, Archbold JA, Ferguson G, Harner T, et al. Is house dust the missing exposure pathway for PBDEs? An analysis of the urban fate and human exposure to PBDEs. Environmental science & technology. 2005 Jul 15;39(14):5121–30.

17. Zota AR, Rudel RA, Morello-Frosch RA, Brody JG. Elevated house dust and serum concentrations of PBDEs in California: unintended consequences of furniture flammability standards? Environmental science & technology. 2008 Nov 1;42(21):8158–64.

18. Watkins DJ, McClean MD, Fraser AJ, Weinberg J, Stapleton HM, Sjödin A, et al. Exposure to PBDEs in the office environment: evaluating the relationships between dust, handwipes, and serum. Environmental health perspectives. 2011 Sep;119(9):1247–52.

19. Dye JA, Venier M, Zhu L, Ward CR, Hites RA, Birnbaum LS. Elevated PBDE levels in pet cats: sentinels for humans? Environmental science & technology. 2007 Sep 15;41(18):6350–6.

20. Venier M, Hites RA. Flame retardants in the serum of pet dogs and in their food. Environmental science & technology. American Chemical Society; 2011 May 15;45(10):4602–8.

21. Sjödin A, Päpke O, McGahee E, Focant J-F, Jones RS, Pless-Mulloli T, et al. Concentration of polybrominated diphenyl ethers (PBDEs) in household dust from various countries. Chemosphere. 2008 Aug;73(1 Suppl):S131–6.

22. Antignac J-P, Cariou R, Maume D, Marchand P, Monteau F, Zalko D, et al. Exposure assessment of fetus and newborn to brominated flame retardants in France: preliminary data. Molecular nutrition & food research. 2008 Feb;52(2):258–65.

23. Lunder S, Hovander L, Athanassiadis I, Bergman A. Significantly higher polybrominated diphenyl ether levels in young U.S. children than in their mothers. Environmental science & technology. 2010 Jul 1;44(13):5256–62.

24. Stapleton HM, Eagle S, Sjödin A, Webster TF. Serum PBDEs in a North Carolina Toddler Cohort: Associations with Handwipes, House Dust, and Socioeconomic Variables. Environmental Health Perspectives. 2012 May 23;120(7).

25. Venier M, Ma Y, Hites RA. Bromobenzene Flame Retardants in the Great Lakes Atmosphere. ES&T,. American Chemical Society; 2012 Jul 31;

26. Drewes JE, Hoppe C, Bellona CL, Wang G. Fate of Chlorinated Flame Retardants in the Environment and Water Treatment. National Ground Water Association; 2006.

27. Oliaei F, King P, Phillips L. Occurence and concentrations of polybrominated diphenyl ethers (PBDEs) in Minnesota environment. Organohalogen compounds. 2002;58:185–8.

28. Hites RA. Polybrominated diphenyl ethers in the environment and in people: a meta-analysis of concentrations. Environmental science & technology. 2004 Feb 15;38(4):945–56.

29. Ross PS. PERSPECTIVE / PERSPECTIVE Fireproof killer whales ( Orcinus orca ): flame- retardant chemicals and the conservation. Canadian Journal of Fisheries and Aquatic Sciences. 2006;63(January 2005):224–34.

30. Babrauskas V, Blum A, Daley R, Birnbaum LS. Flame Retardants in Furniture Foam: Benefits and Risks. Fire Safety Science. 2011;10:265–78.

31. Talley TH. Phases 1&2, UFAC Small Open Flame Tests and Cigarette Ignition Tests. Annual AFMA Flammability Conf. 1995.

32. Mehta S. Upholstered Furniture Full Scale Chair Tests – Open Flame Ignition Results and Analysis. Bethesda, MD: U.S. CPSC; 2012.

33. Babrauskas V. Upholstered Furniture Heat Release Rates: Measurements and Estimation. Journal of Fire Sciences. 1983 Jan 1;1(1):9–32.

34. Nelson GL, Sorathia U, Jayakody C, Myers D. Fire-Retardant Characteristics of Water-Blown Molded Flexible Polyurethane Foam Materials. Journal of Fire Sciences. 2000 Nov 1;18(6):430–55.

35. Gann RG, Babrauskas V, Peacock RD, Hall Jr. JR. Fire conditions for smoke toxicity measurement. Fire and Materials. 1994 May;18(3):193–9.

36. LeMasters GK, Genaidy AM, Succop P, Deddens J, Sobeih T, Barriera-Viruet H, et al. Cancer risk among firefighters: a review and meta-analysis of 32 studies. J. of occupational and environmental medicine / American College of Occupational and Env Medicine. 2006 Nov;48(11):1189–202.

37. Ahrens M. Home Fires That Began with Upholstered Furniture. Quincy, MA: National Fire Protection Association; 2011.

38. Gross L. Special Report: Flame retardant industry spent $23 million on lobbying, campaign donations — Environmental Health News. Environmental health news. 2011 Nov 16;